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the coefficient of friction between the ceramic coating and the steel substrate was measured as 0.3-0.5. for the case of a sliding pair of the ceramic coating and steel substrate, a high contact friction and a subsequent adhesion and cohesion of the coating and substrate are observed. the coefficient of friction between the ceramic coating and the steel substrate increases with the strain rate increasing (fig. 41 ). this is because of the higher temperature in the coating and the higher tensile strain in the coating at a higher strain rate. the cracks of the coating are shown to be initiated at the interface of the coating-steel substrate during the sliding process. as a result, the coefficient of friction increases with the increasing of the strain rate.

the model, developed for solving of boundary value problems describing the deformation and fracture of nanocomposite materials under tension and compression, is based on the principle of the void volume. a set of the integral equations was obtained for the distribution of stresses. it is shown that the strength of the composite increases with the size of the a-type regions and decreases with the size of the c-type regions.

for compounds where the synthetic route is unknown, the spectroscopic data should include, for example, uv/vis and nmr spectra of crude products, for example, from the reflux of the appropriate starting materials, or from simple reactions such as the hydrogenation of an enone or the addition of a halogen to a phenol. documentation of analytical procedures should include, for example, copies of hplc traces and mass spectral data.




a composite under compression and in the final stage of failure (fig. 34 (25)) has been investigated. the plastic deformation of the aluminum matrix enhances to a higher extent at the beginning of the failure process. however, the decreasing of the stresses in the free surface leads to the observed increase in the compressive strength. the plastic deformation at the free surface in the coating is not as intense as in the base, since the coating material has a much higher strength than the base material. the process of failure in the composite is a complex process. deformation at the free surfaces are not as intense as in the case of tension, because of the fact that the stresses in the coating material are lower than in the case of tension. they are also lower due to the fact that compressive forces are exerted on the surface of the coating. in addition, the plastic deformation of the coating material is much more intense than in the case of tension. this is due to the fact that the particles are compressed, so the plastic deformation is forced to spread in the coating. therefore, the amount of stress increases as a function of the distance from the interface. thus, the crack in the coating material is formed in a delayed manner compared to the case of tension, and the crack propagates slower in the case of compression. however, the crack initiates at the end of the free surface of the coating, so the plastic deformation in the coating and at the crack tip is very intense. the plastic deformation in the free surface of the coating increases (as a function of the distance from the interface), so the crack propagates more slowly. the final crack propagation is very slow, since it does not exceed the distance that the plastic deformation in the coating can reach. that is why the crack does not propagate faster in compression than in tension, because the strength of the coating material is greater under tension than under compression. 5ec8ef588b


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